Latent heat characteristics of biobased oleochemical carbonates as potential phase change materials

Abstract

Oleochemical carbonates are biobased materials that were readily prepared through a carbonate interchange reaction between renewable C10–C18 fatty alcohols and dimethyl or diethyl carbonate in the presence of a catalyst. These carbonates have various commercial uses in cosmetic, fuel additive, and lubricant applications. Oleochemical carbonates have not been examined for their applicability as phase change materials (PCM). The latent heats of melting and freezing for a series of symmetrical oleochemical carbonates ranging from 21-37 carbon atoms were evaluated to develop a fundamental understanding of the solid–liquid transitions for utilization in thermal energy storage (TES) applications. The phase transitions and associated thermal properties were determined by differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). Decyl, dodecyl, tetradecyl, hexadecyl, and octadecyl carbonates had peak melting and freezing points of −2.2, 19.3, 33.7, 44.9, and 51.6 and −6.3, 14.3, 28.7, 40.3, and 46.9 °C, respectively. In general, these carbonates exhibited sharp phase transitions and good latent heat properties. The latent heats of melting and freezing for decyl, dodecyl, tetradecyl, hexadecyl, and octadecyl carbonates were 144, 200, 227, 219, and 223 and 146, 199, 229, 215, and 215 J/g, respectively. These carbonates represent novel renewable-based PCM chemicals that compliment fatty acids, fatty alcohols, and their fatty acid esters while providing a potentially valuable biobased alternative to paraffin wax and salt hydrate PCM currently dominating the PCM market.