Late Jurassic paleoenvironmental reconstruction based on stable oxygen isotopes in bulk carbonates from the Qiangtang Basin, eastern Tethys

Abstract

A composite eastern Tethyan oxygen and carbon isotope curve reveals major climate changes through the Late Jurassic. Despite significantly lower values and different amplitudes in scale, the δ18O data from whole-rock carbonates present fluctuant temperature results similar with well-studied composite δ18O curves of diagenetically-screened biogenic calcites, and are possibly acceptable as a paleotemperature proxy. The paleoclimate trends imply a cool global Callovian-Oxfordian transition, a mid-Oxfordian warming, a late Oxfordian cooling, a turbulent Kimmeridgian climate, a warm earliest Tithonian and rapid early Tithonian cooling event. The climate shift from the earliest Tithonian warmth to the middle early Tithonian cool climate was up to 8 °C decrease in some regions. These paleoclimate changes are greatly consistent with the eustatic sea-level changes, biological evolutions and paleoatmospheric CO2 reconstructions, and are recorded by coeval carbon isotope perturbations relating to the organic carbon accumulations in marine sediments. Coupled δ18O and δ13C chemostratigraphy evidence that higher temperatures lead to more rapid continental weathering, increased nutrient-rich runoff into the oceans, and intensified marine productivity, resulting in increased organic‑carbon burial and more positive δ13C values in limestones. The decrease in primary productivity and burial rates during cooling periods is, in turn, commonly accompanied by low δ13C values.