Abstract

The laser-induced fluorescence (LIF) spectrum of the CCN radical was observed with an Ar+ laser. The laser line of 465.8 nm coincided with two rovibronic transitions: R1 (23.5) and sR21 (12.5) for A2Δi:(010)Φ−X 2Πr:(010)Δ. The LIF spectrum consisted of the resonant series: A2Δi:(010)Φ−X 2Πr: (v1v2v3)Δ, and the collision-induced bands: A2Δi:(010)Π−X 2Πr:(v11v3)Σ+, Σ−. The analysis yielded the vibrational and the vibronic parameters of the ground electronic state X 2Πr.

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