Lanthanide-doped upconversion glass–ceramic photocatalyst fabricated from fluorine-containing waste for the degradation of organic pollutants

Abstract

Fluorine-containing waste is one kind of hazardous waste characteristic by hard disposal and utilization, it is an attractive way to prepare for fluoride-based luminescent matrix. In this work, to realize the high value-added utilization of fluorine-containing waste and reduce cost of the raw materials for preparation near-infrared (NIR) glass–ceramic (GC) photocatalyst, the pure fluoride of luminescent matrix was replaced by introducing fluorine-containing waste. The waste contained NIR GC photocatalyst was synthesis by the method of facile in-situ etching of an upconversion GC with HCl, which possesses core–shell structure, where the GC micro-powder including optically active centers lanthanides doped CaF2 nanocrystals are displayed as the core, and the BiOCl is as the superficial coating. The upconversion emission performance of CaF2 based luminescent matrix in photocatalyst is not weakened with HCl etching. NIR GC photocatalyst has high methyl orange and enrofloxacin degradation rate of 86 % and 82 % over 180 min after NIR light irradiation, respectively. The UV–Vis–NIR photocatalytic activity was enhanced degradation rate (93 % in 15 min) of enrofloxacin compared with those of commercial P25 and BiOCl. In addition, the photocatalyst had stable photocatalytic activity and it also can be regenerated. The study provided references for high value-added utilization fluorine-containing waste.