Abstract

Complexes of triphenylarsine oxide with yttrium and lanthanide nitrates have been prepared and studied. The following stoichiometries were obtained: M(NO 3) 3(OAsPh 3) 2EtOH, M(NO 3) 3(OAsPh 3) 3 and M(NO 3) 3(OAsPh 3) 4. Triphenylarsine oxide is more strongly bound to these metal ions than is triphenylphosphine oxide; the metal-ligand bond is almost entirely of an ion-dipole character. The i.r. spectra are discussed, especially with respect to the detailed behaviour of v aso.

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