Laminated composite fabricated using high-performance polyamine thermoset: Ultra heat resistance and excellent mechanical property

Abstract

Developing polymer composites that can work in harsh environment are important for advancing materials industry. However, the composites generally based-on epoxy or phenolics resins that can endure both extremely high and low temperature are still rather limited. In this work, melamine-hexamethylenediamine (MH) thermoset which is structurally different from conventional matrices was used as matrix resin for woven glass fiber reinforced MH (GFRMH) laminated composite. Owing to the excellent thermostability (Td ≈ 460 °C) and interfacial compatibility of the MH matrix, the fabricated composites exhibited exceptional resistance to extreme temperature and mechanical performances, which are superior to that of the representative commercial epoxy-based composites. Particularly, the heat deflection temperature (HDT) of GFRMH was above 300 °C which is much higher than that of the representative high-performance commercial composites (220–270 °C). Moreover, GFRMH composite exhibited excellent retainability even at 425 °C while severe carbonization and delamination occurred to all the selected commercial products. Further, the GFRMH laminate exhibited flexural strength of 541 MPa at room temperature, higher than that of the commercial products by 80–160 MPa. Remarkably, the flexural strength increased to 852 MPa at 77 K without declining of toughness, suggesting the excellent resistance to cryogenic temperature. In summary, the results of the study disclosed the suitability of MH resin as a new matrix of glass fiber reinforced engineering materials.