Abstract

Ice desorption affects the evolution of the gas-phase chemistry during the protostellar stage, and also determines the ice composition of comets forming in circumstellar disks. From observations, most volatile species, including CO2 , are found in H2 O-dominated ices. In this study, the desorption of CO2 mixed in H2 O ice and the impact of ice thickness, mixture ratio and heating rate are experimentally determined. The results are used to parametrize an extended three-phase model (gas, ice surface and ice mantle) which describes ice mixture desorption using rate equations and a minimum number of free parameters. The model can be used to predict the evolution in thickness and concentration of volatile-rich H2 O ice during infall of icy grains around protostars.

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