Abstract
The kinetics of three-dimensional radical copolymerization of methyl methacrylate and divinyl sulfide in the presence of the iniferter N,N′-bis(vinyloxyethyl)thiuram disulfide has been studied. The living chain mechanism of the process performed in the presence of the iniferter is verified by precision isothermal calorimetry. Conditions are found for more efficient kinetic parameters of the pseudoliving three-dimensional radical copolymerization of methyl methacrylate and divinyl sulfide carried out in the presence of the iniferter-AIBN initiating system. General kinetic features and differences in the pseudoliving polymerization of methyl methacrylate and its copolymerization with divinyl sulfide are ascertained.
Published Version
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