Abstract
A novel porous biomorph-genetic composite of α-Fe2O3/Fe3O4/C (PBGC-Fe/C) with eucalyptus wood template was prepared, characterized and tested for its sorption capacity of As(V) from aqueous solution. The result indicated that the PBGC-Fe/C material retained the hierarchical porous structure of eucalyptus wood with three different types of pores (widths 70∼120, 4.1∼6.4 and 0.1∼1.3 μm) originating from vessels, fibres and pits of the wood, respectively. Its surface area was measured to be 59.2 m2/g. With increasing initial As(V) concentration from 5 to 100 mg/L, the amounts of As(V) sorbed on the pulverized PBGC-Fe/C sorbent ( 3 mm) were determined to be 0.50, 0.99 and 2.49 mg/g, respectively, which exhibited a similar average value to those of fine particles or nanoparticles of iron oxides. The sorption could well be described by the pseudo-second-order kinetic equation. The equilibrium data were found to follow Freundlich as well as Langmuir isotherms.
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