Abstract
Under kinetic conditions, monomeric Cr(VI) has been found kinetically active in the absence of bipy while in the bipy-catalyzed path, Cr(VI)-bipy complex has been suggested as the active oxidant. The uncatalyzed path shows the second-order dependence on [H+] while the bipy-catalyzed path shows the first-order dependence on [H+]. Both the uncatalyzed and bipy-catalyzed paths show the first-order dependence on [propan-2-ol]T and [Cr(VI)]T. The bipy-catalyzed path is the first order in [bipy]T. Cetylpyridiniumchloride inhibits the reactions while sodium dodecyl sulfate catalyzes the reactions in the presence and in the absence of bipy.
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