Abstract
The kinetics of the reactions of carbon disulphide with triethylphosphine and diethylphenylphosphine are studied in solutions of acetonitrile, propiononitrile, isobutyronitrile, benzonitrile, benzyl cyanide, and some of their mixtures. The reaction shows reversible pseudo-first-order kinetics.Activation and equilibrium parameters are discussed in terms of solvent properties.
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