Abstract
Abstract The band widths of the infrared absorption spectra were observed for binary solutions of methyl iodide, methyl cyanide, chloroform, and carbon disulfide. The observed bands are: the v1 fundamental of chloroform in carbon disulfide and in carbon tetrachloride; the v2 fundamental of methyl iodide in methyl cyanide, nitromethane, benzene, carbon disulfide, and carbon tetrachloride; the 2v2 band of methyl iodide in methyl cyanide, and the v8 and 2v8 bands of methyl cyanide in methyl iodide. The concentration dependence of a band width was explained in terms of the concentration fluctuation. The theory was compared with the observed band widths, together with the light-scattering data. A fluctuation volume was related with the intermolecular interactions in these binary solutions.
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