Kinetic studies and conditions optimizations for the removal of direct red 80 dye from wastewater using cotton calyx and iron oxide composite

Abstract

Abstract This study focusses on the adsorption efficiency of cotton pod (Gossypium arboreum) for biosorption of direct red (DR) 80 dye. The effect of dye concentration, pH, shaking time, adsorbent dose and temperature was considered to evaluate the adsorption efficiency of the cheapest raw material on the removal of dye. Various concentrations (10–50 ppm) were examined and maximum percentage removal of the adsorbent was obtained at pH 1 with adsorbent dose of 0.9 g and shaking time of 60 min. To enhance the adsorption efficiency of the adsorbent, the cotton calyx was treated with FeSO4.7H2O and investigated the removal of the raw adsorbent and the composite. It was examined that the removal efficiency of the composite is more than that of raw adsorbent. The composite was more efficient as dye removal reached up to 97%. FTIR of the composite shows an additional peak at 650 cm−1 for presence of Fe-O group and confirmation of composite formation. SEM micrograph showed that the particles in composite are more packed compared to the raw adsorbent. Mathematical models were applied and kinetic studies also have been done to provide better results regarding to the experimental data. It is concluded that the prepared adsorbent could be used as a tool for the removal of toxic pollutants from textile wastewater.