Abstract
Bulk free-radical polymerization of methyl methacrylate was studied by differential scanning calorimetry (DSC). Dependence of monomer conversion on time was calculated from the experimental DSC data. Proposed model, composed of two contributions to the monomer conversion was found to excellently describe experimental data. First contribution originates from polymerization according to classical theory of radical polymerization and the other from polymerization during the autoacceleration.
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