Abstract
A study was made of kinetic features of radical polymerization of N,N-dialkyl-N,N-diallylammonium chlorides in dilute, dilute-methanol and methanol solutions. It was found that on increasing the initial concentration of the monomer, the rate of polymerization increases suddenly and in a non-linear manner. Experimental results prove that the cause of the effect observed is the reduction of the rate constant of chain termination on increasing monomer concentration, as a consequence of comparatively high values of relative viscosity of initial monomer solutions.
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