Kinetic evaluation of ZnO/TiO2 thin film photocatalyst in photocatalytic degradation of Orange G

Abstract

Abstract The ZnO/TiO2 solution of the thin-film photocatalyst was prepared by using the sol-gel method. The prepared solution was coated on a quartz plate by using the dip-coating method. For the characterization of synthesized ZnO/TiO2 photocatalyst, SEM-EDS, XRD and chronoamperometry measurements were used. To determine photocatalytic activity and kinetic model studies, the degradation of Orange G dye which is frequently used in the textile industry on ZnO/TiO2 photocatalyst was investigated. Using the results of kinetic experiments by examining the effects of different initial dye concentrations, temperature and light intensities, the degradation of Orange G dye on ZnO/TiO2 photocatalyst was found to be in accordance with the Network Kinetic Model, and the calculated equilibrium constant and activation energies of the ZnO/TiO2 thin film photocatalyst are 20.02 and 16.16 kJ/mol, respectively.