Killing Two Birds with One Stone: Coating Ag NPs Embedded Filter Paper with Chitosan for Better and Durable Point-of-Use Water Disinfection

Abstract

In this study, porous chitosan (CS) coated Ag NPs embedded filter paper (CAEFP) was fabricated for point-of-use water disinfection application. Thanks for the presence of CS coating, the tensile strength of the CAEFP in wet condition was found to be 1.8 MPa, 700% increase compared with where there was no CS coating, making it much more durable. In addition, the coating with CS could greatly boost the Ag NPs loading without worrying about the excessive release of Ag into the treated water, thereby significantly improving the bactericidal efficiency but still be safe to drink in terms of Ag release. Furthermore, by controlling the amount of CS used, the flow rate and bactericidal efficiency of the CAEFP could be manipulated (customized). When the CS content increased from 0.5 to 2.0 wt %, the flow rate of CAEFP would drop from 9.3 to 0.53 L/min/m2, and the bactericidal efficiency against Escherichia coli and Bacillus subtilis could improve from 4 and 3.6 to 4.9 and 4.8 log reduction, respectively. At optimum condition, the total Ag in treated water by CAEFP was below 45 μg/L, only 1/10 of that from Ag NPs loaded filter paper without CS coating, half of the WHO drinking water requirement (<100 μg/L). Natural surface water samples were used for the demonstration of the bactericidal performance of the CAEFP. Both the total bacterial and E. coli counts met the WHO standard.