Kill two birds with one stone: Ceramisite production using organic contaminated soil

Abstract

Disposal of organic-contaminated soil through ceramsite production can not only generate ceramsite with acceptable properties but also completely remediate the organic-contaminated soil owing to high treatment temperature. However, the removal mechanism of organic pollutants and the gas-solid phase distribution of the pollutants remain unclear. In this study, coking contaminated soils with high concentrations of polycyclic aromatic hydrocarbons (PAHs) and petroleum hydrocarbon (PHC) were used to prepare ceramsite at 1160 °C. The quality of ceramsite met the required product standard when the disposal ratio of contaminated soil was up to 60%. The concentration of PAHs and PHC in the soil was 57.7 mg kg-1 and 255 mg kg-1. After the experiment, almost no PAHs and PHC were found in the ceramsite. High-ring PAHs were dominant in the flue gas when using model soil spiked with PAHs. Computed tomography scanning indicated that cracks developed in the ceramsite when the temperature was higher than 200 °C. High-temperature in-situ thermal analysis showed that when the temperature was increased to 400 °C, the pollutant from the interior of ceramsite would flow into the flue gas with the released volatile matter. Thermal desorption and degradation of PAHs were the main mechanisms of pollutant removal.