Abstract

Photoelectrochemical cells are at the forefront of promising methods of direct solar hydrogen production. It may become the best solution to produce storable chemical energy in a sustainable way and an alternative for combining photovoltaics with expensive storage systems like batteries. This environmentally friendly system based on an earth-abundant kesterite monograins with low processing cost and the outstanding semiconductor properties of single crystals, enables large-scale commercialization. This study aims to evaluate Cu2ZnSn(SxSe1-x)4 monograins with x = 0 to x = 1 for photovoltaic and photoelectrochemical water splitting applications.

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