Abstract

The first-order difference method of neutron diffraction has been applied to a 4 molal solution of potassium chloride in heavy water. Isotopes of 39K and 41K were present in different amounts in the two samples enabling the derivation of the total radial distribution function for the potassium ion. The results show that the K +-water configuration is significantly weaker than that observed for the Li + ion. It is also shown that recent results of computer simulation are in good agreement with experiment.

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