Abstract
We study jamming in model freely rotating polymers as a function of chain length N and bond angle θ_{0}. The volume fraction at jamming ϕ_{J}(θ_{0}) is minimal for rigid-rodlike chains (θ_{0}=0), and increases monotonically with increasing θ_{0}≤π/2. In contrast to flexible polymers, marginally jammed states of freely rotating polymers are highly hypostatic, even when bond and angle constraints are accounted for. Large-aspect-ratio (small θ_{0}) chains behave comparably to stiff fibers: resistance to large-scale bending plays a major role in their jamming phenomenology. Low-aspect-ratio (large θ_{0}) chains behave more like flexible polymers, but still jam at much lower densities due to the presence of frozen-in three-body correlations corresponding to the fixed bond angles. Long-chain systems jam at lower ϕ and are more hypostatic at jamming than short-chain systems. Implications of these findings for polymer solidification are discussed.
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