Abstract
The binary isotropic collision-induced scattering spectra of the gaseous tetrafluoromethane has been measured in absolute units in the 50--150 ${\mathrm{cm}}^{\mathrm{\ensuremath{-}}1}$ frequency range. Corresponding theoretical intensities taking into account multipolar polarizabilities have been calculated in a semiclassical way. From a comparison with experiment, the independent components of dipole-quadrupole and dipole-octupole polarizability tensors have been estimated. They have been compared with those previously deduced from depolarized spectrum and with recent theoretical ab initio calculations.
Full Text
Published Version (
Free)
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call