Abstract
The new inclusion complex bis(tetra– n–propylammonium) squarate–urea–water (1/6/2), [( n–C 3H 7) 4N +] 2C 4O 4 2−·6(NH 2) 2CO·2H 2O, has a three-dimensional anionic host framework containing large uni-directional channels that accommodate the hydrophobic cations. Replacement of its dumbbell-shaped hydrogen-bonded moiety (H 2O–C 4O 4 2−–H 2O) by the equivalent synthon (H 2O–Br −) 2 generates the known crystal structure of ( n–C 3H 7) 4N +Br −·(NH 2) 2CO·H 2O, thereby providing an interesting example of isostructurality in the realm of inclusion compounds.
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