Abstract
Abstract The isomerism of α-benzilmonoxime I is investigated by the measurements of their mass spectra and the integrated ion current curves at temperature 200°C. Evidences of isomerisation and Beckmann rearrangement reactions of I under electron impact source are given. The high stability of solid I on storage is explained on the basis of hydrogen bonding. A comparative stability constant as measured kinetically in term of half life period between I and benzophenone oxime IV is investigated.
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