Isolation and reactivity of metal-containing monomers. 10. Dissociation of metal-containing monomers in water and organic solvents

Abstract

1. The degree of dissociation of metal-containing monomers (MCMs) — the acrylates of transition and non-transition metals — decreases in going from aqueous to nonaqueous solutions; this allows the exclusion of the formation of “metal-free” products in the reactions of the MCMs in nonaqueous media. 2. The dissociation constants of vinyl-substituted alkoxides of Ti(IV) in benzene solutions were determined; it was noted that they were decreased by comparison with the symmetrical orthotitanates.