Preparation and reactivity of metal-containing monomers. 9. Low-temperature postradiation polymerization of metalcontaining monomers in devitrification of the matrices

Abstract

1. The features of phase transitions of metal-containing monomers (MCM) of Ni(II), Co(II), Cu(II), Cr(III), and Mn(II) acrylates and acrylamide complexes and Ti(IV) alkoxy derivatives were investigated in the region of low temperatures in bulk and in 10% ethanol solution. 2. The possibility of postradiation polymerization of MCM in devitrification in the matrix and alcohol solutions was demonstrated. 3. Postpolymerization of MCM in devitrification takes place less efficiently than postpolymerization of their analogs containing no metal atoms.