Is monolithic configuration superior to random packing in a fixed bed reactor for CLC like processes?

Abstract

In light of the geometric deficiencies and diffusion constraints of conventional packed-bed reactors, the potential application of monolithic configurations in fixed-bed reactors was explored using the structure-resolved CFD approach. This work delves into how geometric features of fixed beds influence flow patterns and related transport phenomena. To assess the performance of mass transfer and heterogeneous reactions in different configurations, we conducted simulations of fixed-bed chemical looping combustion (CLC) processes, in which a simplified model of non-catalytic gas-solid reactions is implemented to reduce the computational costs. Our findings highlight the importance of face contact between reaction tube and the monolithic structure, which effectively eliminates the inherent wall effects of random packing and enhances the radial heat conduction. More uniform geometry in the monolithic configuration naturally suppresses violent interstitial channeling flow in the random packing. Notably, the honeycomb configuration demonstrates an exceptionally low pressure drop, about two orders of magnitude smaller than that of the Raschig ring packing, and the designable monolithic configurations offers the potential to further reduce the pressure drop with enlarged voidage. Open-cell foams exhibit excellent convective and radial heat transport properties, promote homogeneous flow fields, and demonstrate superior performance in conjugate transport and heterogeneous reactions.