Is biomagnetic leaf monitoring still an effective method for monitoring the heavy metal pollution of atmospheric particulate matter in clean cities?

Abstract

The development of a reasonable method for predicting heavy metals (HMs) pollution in atmospheric particulate matter (PM) remains challenging. This paper presents an elution-filtration method to collect PM from the surface of Osmanthus fragrans in a very clean area (Guiyang, China). The aim is to evaluate the effectiveness of biomagnetic leaf monitoring as a simple and rapid method for assessing HMs pollution in clean cities. For this purpose, we determined the magnetic parameters and concentrations of selected HMs in PM samples to investigate their relationships. The results showed that the magnetic minerals in PM samples were mainly low coercivity ferrimagnetic minerals, with a small amount of high coercivity minerals. The types of magnetic minerals were generally single, and the magnetic domain state was pseudo-single domain (PSD). There was a significant correlation between magnetic parameters and the heavy metal (HM) concentrations in PM. Low-field magnetic susceptibility (χ) could be used as an ideal proxy for determining anthropogenic HM pollution. Traffic emissions were the main atmospheric pollution source in urban Guiyang. Due to the incomplete traffic network and large traffic flow, traffic congestion (TC) often occurred at road intersections in the northwest and southwest corners of the city, resulting in the highest concentration of magnetic minerals and the most severe PM pollution. To mitigate atmospheric PM pollution and protect public health, it is strongly recommended that municipal authorities prioritize urban planning and traffic management to address TC. Measures should be implemented urgently to alleviate stop-and-go traffic.