Abstract
The complex [(C5Me5)RuCl(dippe)](dippe = l,2-bis(diisopropylphosphino)ethane) reacts with alk-1-ynes in MeOH in the presence of NaBPh4 yielding the metastable hydrido-alkynyl derivatives [(C5Me5)Ru(H)(CCR)(dippe)][BPh4](R = CO2Me, SiMe3 or Ph), intermediates in the formation of the corresponding vinylidene complexes, to which these compounds rearrange both in solution and in the solid state.
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