Abstract

A set of V–(4–8)Cr–(0–4)Ti alloys was fabricated to survey an optimum composition to reduce the radioactivity of V–Cr–Ti alloys. These alloys were subjected to nano-indenter tests before and after 2-MeV He-ion irradiation at 500 °C and 700 °C with 0.5 dpa at peak damage to investigate the effect of Cr and Ti addition and gas impurities for irradiation hardening behavior in V–Cr–Ti alloys. Cr and Ti addition to V–Cr–Ti alloys for solid–solution hardening remains small in the unirradiated V–(4–8)Cr–(0–4)Ti alloys. Irradiation hardening occurred for all V–Cr–Ti alloys. The V–4Cr–1Ti alloy shows the highest irradiation hardening among all V–Cr–Ti alloys and the gas impurity was enhanced to increase the irradiation hardening. These results may arise from the formation of Ti(CON) precipitate that was produced by He-ion irradiation. Irradiation hardening of V–Cr–1Ti did not depend significantly on Cr addition. Consequently, for irradiation hardening and void-swelling suppression, the optimum composition of V–Cr–Ti alloys for structural materials of fusion reactor engineering is proposed to be a highly purified V–(6–8)Cr–2Ti alloy.

Highlights

  • Vanadium alloys are attractive blanket structural materials in fusion power systems because of their low induced activation characteristics, high-temperature strength, good compatibility with a liquid lithium environment and high thermal stress [1,2,3]

  • Critical issues of vanadium alloys, such as corrosion and oxidation have been resolved by Cr and Ti addition to the vanadium matrix, and recent efforts have focused on developing the V–4Cr–4Ti alloy as a candidate alloy for Li-blanket systems in fusion reactors [4,5]

  • The effect of gas impurity level for irradiation hardening appears in irradiation hardening of V–4Cr–1Ti alloys irradiated at 500 ◦ C and 700 ◦ C, and the highly purified V–Cr–Ti alloys reduce the irradiation hardening as shown in Figures 2 and 4

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Summary

Introduction

Vanadium alloys are attractive blanket structural materials in fusion power systems because of their low induced activation characteristics, high-temperature strength, good compatibility with a liquid lithium environment and high thermal stress [1,2,3]. Critical issues of vanadium alloys, such as corrosion and oxidation have been resolved by Cr and Ti addition to the vanadium matrix, and recent efforts have focused on developing the V–4Cr–4Ti alloy as a candidate alloy for Li-blanket systems in fusion reactors [4,5]. The susceptibility of V–4Cr–4Ti alloys to low-temperature embrittlement during neutron irradiation may limit their application in low-temperature (

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