Abstract

AbstractA convenient iron‐catalyzed oxidative dehydrogenative coupling reaction of 3,4‐Dihydro‐1,4‐benzoxazin‐2‐ones with malonic esters or ketones was performed under mild reaction conditions to construct alkyl–alkyl C(sp3)−C(sp3) bonds. This transformation can be catalyzed efficiently by magnetically recoverable iron nanoparticles and the catalyst can be recycled easily for 7 times without decreasing activity.magnified image

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