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https://doi.org/10.1021/ol201907w
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Cite Journal: Organic Letters |  Publication Date: Aug 3, 2011 |
 Citations: 168 |  License type: cc-by-nc |
Affiliation: Waseda University
A cationic Ir(I)-tolBINAP complex catalyzed an enantioselective C-C bond formation initiated by secondary sp(3) C-H bond cleavage adjacent to a nitrogen atom. The reaction of 2-(alkylamino)pyridines with various alkenes gave chiral amines in good yields with high enantiomeric excesses.
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