Abstract

The ionization of potassium Rydberg atoms with $n\ensuremath{\sim}388$ and $n\ensuremath{\sim}520$ by pulsed electric fields whose durations, which range from \ensuremath{\sim} 2 to \ensuremath{\sim} 110 ns, span the transition from the short-pulse to the long-pulse regime is investigated experimentally and the data compared with the results of classical trajectory Monte Carlo calculations. We observe excellent agreement between theory and experiment providing a benchmark test for the validity of the classical limit of ionization. Very-high-$n$ atoms provide an excellent tool with which to probe the response of atoms to pulsed electric fields in the short-pulse regime.

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