Abstract
We report studies of the temperature dependence of the Knight shift of Cu atoms near to Cr atoms in dilute $\mathrm{Cu}\mathrm{Cr}$ alloys. Comparison with $\mathrm{Cu}\mathrm{Mn}$ and $\mathrm{Cu}\mathrm{Fe}$ leads us to propose electronic structures for these important systems. We confirm the general picture of Hirst: The atoms have integral numbers of $3d$ electrons and obey Russell-Sanders coupling, but the sign of the crystal field is opposite to that of Hirst, and Fe has seven rather than six $3d$ electrons.
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