Abstract
Conductivities have been measured by the vector impedance method for the layered compounds anhydrous α-zirconium phosphate, Zr(HPO 4) 2, and several of its sodium ion phases. The values of the ionic diffusion coefficients are of the order of 10 −6-10 −8 cm 2/s at 200°C and activation energies range from 15.6 cal/mol for Zr(HPO 4) 2 to 18.6 cal/mol for ZrHNa(PO 4) 2. Comparisons are made with literature values of conductivity and self-diffusion coefficients for Zr(NaPO 4) 2·3H 2O and kinetically determined diffusion coefficients for the phases containing both sodium and hydrogen ions.
Full Text
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call