Ion-Specific Effects on the Elongation Dynamics of a Nanosized Water Droplet in Applied Electric Fields.

Abstract

We report an all-atom molecular dynamics study of the structures and dynamics of salty water droplets on a silicon surface under the influence of applied electric field. Our simulation results support ion-specific effects on the elongation dynamics of salty nanodroplets, induced by the field. This feature has not been explored up to now in monovalent salts. Nevertheless, the importance of ion-specific effects is widely confirmed in biological and colloidal systems. In particular, the increase of salt concentration enhances the effect of the nature of ions on the wetting properties of droplets. In the presence of electric field (0.05 V Å-1), a complete spreading is implemented in a short time for different droplets at a concentration of 1 M, and the droplet morphology is stable, observed at long time scales. However, a higher salt concentration of 4 M considerably suppresses the spreading process owing to the increase of surface tension. It was found that the NaCl droplet shows deformation oscillations along the external field, but cannot fully wet the substrate surface. By contrast, the CsCl droplet reaches complete elongation rapidly and adopts a steady strip shape. The KCl droplet undergoes frequent transitions between breakup and connection. Additionally, the droplets can be elongated only when the electric field strength exceeds a threshold value. The dipole orientation of interfacial water and the ionic diffusion exhibit ion-specific dependences, but the hydrogen bond network is scarcely disturbed, excluding a concentration-dependent effect.