Abstract
The quasi-lattice model for quaternary reciprocal systems of molten salts, previously developed for association processes in mixed solvents, has been modified to apply to an association process involving a “mixed ligand” in a pure salt as solvent. The association energies, determined from e.m.f. measurements in the range 620–720 K, for the association of silver(I) with chloride-bromide mixtures in molten sodium nitrate, are in satisfactory agreement with the predictions of the model. The very small, but significant, discrepancies between calculated and experimental association energy values show the same trend as those previously found for the mixed solvent systems.
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