Abstract
The photolysis of 1-iodoanthraquinone anion radical in acetonitrile containing tetrabutylammonium iodide (TBA+I–) is unaffected by changes in [TBA+I–] up to 0.2 mol dm–3, confirming that the previously observed iodide ion quenching results from capture of photogenerated aryl radicals by the nucleophilic iodide, a process analogous to that in nucleophilic aromatic substitution by the SRN1 mechanism.
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