Abstract
Abstract Nucleophilic vinylic substitutions of (Z)-(β-halovinyl)phenyliodonium salts with tetrabutylammonium halides proceed in a stereoselective manner with retention of configuration yielding vicinal (Z)-vinyl dihalides. This reaction competes with nucleophilic aromatic substitutions. Similar competition was observed in the reactions with potassium halides/cuprous halides.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have