(Invited) Electrosynthesis of Long-Chain Hydrocarbons and Oxygenates

Abstract

The electroreduction of CO(2), driven by renewable electricity, can be used to sustainably generate synthetic fuels and chemical feedstocks. Long carbon chain molecules are of particular interest due to their high energy densities and utilities. However, to date, most of the CO(2) reduction products formed are limited to C2 and C3. Herein, we discuss the development of electrocatalysts for the reduction of CO(2) to long-chain oxygenates and hydrocarbons, and their underlying reaction mechanisms.CO(2) electroreduction has been previously reported to yield a range of carbonaceous products including alcohols, hydrocarbons and carboxylic acids. Interestingly, esters, an important family of organic compounds, have not been formed. We show how C3–C6 acetate esters could be produced from CO reduction in a membrane electrode assembly (MEA) cell. The near water-free reaction environment and the high local pH in the MEA played key roles in forming the esters with a Faradaic efficiency of 22 % and a current density up to −55 mA cm−2. We also disclose that inorganic nickel oxygenate (INO)-derived electrocatalysts can reduce CO2 to linear and branched C3-C6 hydrocarbons with Faradaic efficiencies up to 6.5%. We identified Niδ+ active sites which bind CO moderately. Our results show that Ni atom polarization to be important in hindering CO poisoning of nickel and thus facilitating CO2 reduction to a wider pool of valuable products.Finally, we show how MgAl layered double hydroxide (LDH) nanosheets ‘House-of-cards’ structures help to disperse CuO-derived Cu (OD-Cu) catalysts. The porous structures formed enhanced CO gas percolation through the catalyst layer. OD-Cu dispersed by the ‘House-of-cards’ structures catalysed CO electroreduction to C2+ products with a partial current density that is an order of magnitude higher than that shown by the unsupported OD-Cu.