Abstract
We report the fluorescent properties of 3D localized structure with size near the diffraction limit induced by femtosecond direct laser writing (DLW) in Yb3+ and silver-containing phosphate glass. The homogenous dispersion of the silver ions and Yb3+ ions in the glass matrix before DLW was evidenced using photo-luminescent spectroscopy and time-resolved spectroscopy. Using high repetition rate femtosecond DLW, the inscription of 3D visible and near-infrared fluorescent patterns formed by co-localization of silver cluster and Yb3+ ions was demonstrated. The local refractive index change associated with the formation of silver clusters is dependent on the laser irradiance. Confocal micro-luminescent spectroscopy for excitation wavelength in the visible range shows efficient emission of Yb3+ only on DLW induced 3D fluorescent patterns. This finding demonstrated the ability to perform thanks to DLW laser a resonant efficient nonradiative energy transfer from silver clusters to Yb3+ and allows 3D writing of near-infrared luminescence.
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