Abstract

Methods of spontaneous crystallization on a platinum loop, modified VPA method, solid phase synthesis, X-ray powder diffraction analysis and chemical analyses were used to study phase formation in the Li, Ba//BO2, F ternary reciprocal system and the base of the BaO–B2O3–Li2O prism of quaternary reciprocal system Ba, B, Li//O, F. In these systems the fields of primary crystallization of β-BaB2O4 were determined and a promising solvent for crystal growth was found. A series of experiments were carried out on the growth of bulk barium borate crystals in the system BaB2O4–LiF.

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