Abstract

In this manuscript, the durability of the E-glass/epoxy composite was determined under a seawater environment. The effect of harsh environment was investigated in terms of seawater absorption, microstructure and degradation in mechanical properties. E-glass epoxy composite specimens were conditioned in gulf seawater at 23 °C, 65 °C and 90 °C for the period of 12 months. It was observed that the mass of the samples increased after the immersion of 12 months at 23 °C and 65 °C whereas it reduced at 90 °C. The salt deposition was observed at the surface of specimens without any crack for the seawater conditioning at 23 °C and 65 °C. The swelling and crack formation were significantly visible on the surface of the specimen immersed for 12 months at 90 °C. It indicates that the degradation mechanism accelerated at elevated temperature results fiber/matrix debonding. The tensile test indicates slight variation in the elastic modulus and reduction in strength of E-glass epoxy composite by 1% and 9% for specimens immersed at 23 °C and 65 °C respectively. However, at 90 °C, the tensile strength sharply decreased to 7% and elastic modulus significantly increased in the exposure of 12 months. A prediction approach based on a time-shift factor (TSF) was used. This model predicted that the strength retention of E-glass/Epoxy composite will be reduced to 7% in 450 years after immersion in seawater at 23 °C. Lastly, the activation energy for the degradation of the composite was calculated.

Highlights

  • Glass Fiber-Reinforced Polymer (GFRP) composites are commonly used in automobile, aerospace and marine industries because of their high strength to weight ratio, stiffness and durability

  • The color of the specimen changed from black to gray for the specimen exposed at 90 ◦ C whereas no change in color was observed for the specimen immersed at 23 ◦ C and 65 ◦ C

  • The results indicate that the value of elastic modulus varied between 34.07 GPa and 47.38 GPa in the entire conditioning duration

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Summary

Introduction

The swelling and crack formation were significantly visible on the surface of the specimen immersed for 12 months at 90 ◦ C. It indicates that the degradation mechanism accelerated at elevated temperature results fiber/matrix debonding. The tensile test indicates slight variation in the elastic modulus and reduction in strength of E-glass epoxy composite by 1% and 9% for specimens immersed at 23 ◦ C and 65 ◦ C respectively. A prediction approach based on a time-shift factor (TSF) was used This model predicted that the strength retention of E-glass/Epoxy composite will be reduced to 7% in 450 years after immersion in seawater at 23 ◦ C.

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