Abstract
31P{ 1H} NMR spectra of metal–organic [( n Bu 3P) m MO 2CMe] (M = Cu, Ag; m = 1, 1.5, 2, 2.5, 3, 3.5, 4) have been studied in the temperature range of 308–178 K. Exchange parameters were determined for the appropriate silver(I) complexes. Possible ligand exchange mechanisms based on dissociative and associative processes are discussed.
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