Investigation of the effects of expectation values for radii on the determination of transition probabilities using WBEPM theory

Abstract

Transition probabilities for some excited s-p and p-s transition arrays of neutral nitrogen have been calculated using the weakest bound electron potential model theory (WBEPMT) for the investigation of effects of expectation values of radii.We have used both numerical non-relativistic Hartree-Fock (NRHF) wave functions and numerical Coulomb approximation (NCA) wave functions to calculate expectation values of radii. The transition probability results obtained using the parameters determined with two different wave functions agree well with each other and accepted values taken from NIST for low values of transition probability. However, the NRHF wave functions present better results for p-s transitions, while NCA wave functions are better in s-p transitions for large values of transition probability.