Abstract

The formation of stable surface methoxy groups in various zeolite-catalysed reaction processes has been widely accepted as an important intermediate stage and the understanding of such an intermediacy is of great significance. 13C magic-angle-turning (MAT) NMR experiments, in conjunction with theoretical calculations of 13C shielding tensors, are employed to investigate the chemical and electronic nature of methoxy groups on H-SAPO-34.

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