Abstract
Abstract Solution-processed tungsten disulfide (WS2) is demonstrated as a promising resistive switching layer for flexible resistive random access memory (RRAM) devices. For this study, WS2 nanoparticle solution was prepared by liquid exfoliation process from WS2 powder and comprehensive material investigation was performed to understand the suitability for device fabrication through morphologies and electronic behavior. Devices were fabricated on indium tin oxide (ITO) coated flexible polyethylene terephthalate (PET) with ITO acting as bottom electrode (BE) and silver (Ag) deposited as top electrode (TE) with thin film of WS2 prepared by spin coating as an active layer between electrodes. These fabricated flexible RRAM devices exhibited resistive switching characteristics with low operating voltages (V SET ∼0.5 V and V RESET ∼−1.4 V) over 100 consecutive cycles, along with impressive retention time of ∼104 s and high I ON/I OFF of ∼104. The performance variation of these devices was also investigated upon bending at radii of 12 mm and 5 mm indicating consistent switching, however a decay in LRS was observed after 250 s upon investigation of retention. These findings suggest that solution-processed thin films of WS2 nanomaterial can act as a promising switching layer for flexible electronics.
Published Version
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