Investigation of miscibility and phase structure of a novel blend of poly(lactic acid) (PLA)/acrylic rubber (ACM) and its nanocomposite with nanosilica

Abstract

ABSTRACTIn this work, a novel polymer blend containing poly(lactic acid) (PLA) as a biocompatible and biodegradable thermoplastic and acrylic rubber (ACM) is prepared and the miscibility and phase structure of the blend and its nanocomposite (PLA/ACM/nanosilica) are investigated through theoretical and experimental methods. To predict the phase diagram of the blend, a compressible regular solution model was employed, in which an upper critical solution temperature was observed. The model predicted that PLA/ACM blends are immiscible over the whole composition range at temperatures below 260 °C. Performing scanning force microscopy on the blend showed phase separated structures for the blends containing different amounts of the PLA and ACM. This was in accordance with the results of dynamic mechanical analysis, which revealed two distinct glass transition temperatures for the studied blends. The effect of nanometer sized silica particle on morphology and rheological properties of these blends was also investigated. Scanning force microscopy results showed much reduction of droplet size in the blends containing 2 wt % nanosilica. This was attributed to the suppression effect of nanosilica on the droplets coalescences. Rheological measurements confirmed the interaction of both components with the silica nanofiller. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 45499.