Investigation of Hybrid Nanoparticle-Acid Fluids (HNAFs): Influence of Wettability and Interfacial Tension Mechanisms in Harsh Carbonate Reservoirs for Improved Oil Recovery.

Abstract

Over the past few years, there has been significant interest in the potential of hybrid nanoparticle-acid fluid (HNAFs) for improved oil recovery. This comprehensive study investigates the effects of nanoparticles and acid on interfacial tension (IFT) to establish a relationship between brine properties and the oil/brine IFT. This investigation is one of the first regional studies conducted utilizing candidate field data from the Middle East. Based on the literature review and screening studies conducted, a seawater (SW)-based HNAF was formulated with nanoparticles (SiO2, Al2O3, and ZnO) and HCl to measure their effect on IFT. A total of 48 formulations of HNAFs, nanofluids with and without acid, were analyzed with crude oil from a candidate field. IFT measurements were subsequently conducted using the pendant drop method under ambient conditions and in a high-pressure, high-temperature reservoir environment. Results showcased that IFT reduction was observed by increasing the acid concentration with SiO2 and Al2O3, although a reverse trend was observed with ZnO. Moreover, it was observed that IFT varied with increasing concentrations of nanoparticles, and at certain acid concentrations, IFT reduced significantly with higher nanoparticle concentrations. From the Amott studies, a clear signature was achieved, with ZnO exhibiting a total of 31.4% oil recovery, followed by SiO2 (27.3%) and Al2O3 (23.7%). The results of this study may assist in defining a screening criterion for future displacement (oil recovery) studies involving the presented nanoparticles. The results also reveal further the mechanisms involved in IFT reduction by hybrid nano-acid fluids and their potential for significant applications in the Middle East.