Investigation of adsorption performance of calcium oxide particles upon various treatments.

Abstract

This study describes the improvements of adsorption capacities for raw calcium oxide (CaO) particles subjected to ultrasonication, activation with nitric acid and thermal treatments. The influence of acids and bases on CaO particle surface was assessed with respect to several variables including treatment methods, adsorption contact times, particle size and specific surface area characteristics, concentration and temperature along with various thermodynamic parameters. Structural analyses and physical characteristics of CaO particles were evaluated using FT-IR and SEM methods. SEM micrographs of samples revealed uniform distributions of CaO particles of average diameter 0.5-2.0µm. The CaO surfaces showed CH3COOH as having the greatest amounts of adsorbate and modeling of the experimental adsorption isotherm data agreed well with the Freundlich adsorption isotherm. Enhancements in adsorption performance of untreated CaO particles were noted with the ultrasonication, activation with HNO3 and thermal treatment processes. The Langmuir-type adsorption demonstrated that single layer adsorption capacities of adsorbate CH3COOH at 25oC on sonicated CaO (386.6mg/g), with nitric acid and thermal activation (354.9 and 320.8mg/g, respectively) were greater than that of the unsonicated CaO (296.3mg/g) particles. Adsorption spontaneities of the processes were confirmed by the decreases in adsorption free energy values, ΔGads0, changing from -16.1 to -17.1kJmol-1 with temperature range 283-338K.